Product ID:LONG RANGER SINGEL GEL PACK, F17-68-5
MSDS Date:05/01/1997
FSC:6810
NIIN:00N092408
Status Code:A
MSDS Number: CJSML

FMC CORPORATION

191 THOMASTON ST
ROCKLAND, ME 04841
US

Emergency Phone: 303-595-9048

Info Phone: 800-521-0390

Cage: 61382

FMC CORPORATION

ROCKLAND, ME 04841 US

Telephone: 800-521-0390; 207-594-3400

Cage: 61382

COMPARTMENT 1 (CONTAINING INGREDIENT 2)

OSHA PEL N/K

ACGIH TLV: N/K

UREA (NOT CLASSIFIED AS DANGEROUS)

CAS: 57-13-6

RTECS: YR6250000

OSHA PEL N/K

ACGIH TLV: N/K

COMPARTMENT 2 (CONTAINING INGREDIENTS 4 TO 7)

OSHA PEL N/K

ACGIH TLV: N/K

TRIS; (TRIS BASE) (NOT CLASSIFIED AS DANGEROUS)

CAS: 77-86-1

RTECS: TY2900000

OSHA PEL N/K

ACGIH TLV: N/K

BORIC ACID (NOT CLASSIFIED AS DANGEROUS)

CAS: 10043-35-3

RTECS: ED4550000

OSHA PEL N/K

ACGIH TLV: N/K

EDTA (NOT CLASSIFIED AS DANGEROUS)

CAS: 60-00-4

RTECS: AH4025000

OSHA PEL N/K

ACGIH TLV: N/K

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

WATER (NOT CLASSIFIED AS DANGEROUS)

CAS: 7732-18-5

RTECS: ZC0110000

OSHA PEL N/K

ACGIH TLV: N/K

COMPARTMENT 3 (CONTAINING INGREDIENT 9)

OSHA PEL N/K

ACGIH TLV: N/K

O; R8; XN;

CAS: 7727-54-0

RTECS: SE0350000

OSHA PEL N/K

ACGIH TLV: 0.1 MG/M3

COMPARTMENT 4 (CONTAINING INGREDIENTS 11 TO 18; ALSO

OSHA PEL N/K

ACGIH TLV: N/K

FORMALDEHYDE (NOT CLASSIFIED AS DANGEROUS)

CAS: 50-00-0

RTECS: LP8925000

OSHA PEL see 1910.1048

ACGIH TLV: N/K

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

N-METHYLOLACRYLAMIDE (MAY CONTAIN ONE OR MORE OF THE

CAS: 924-42-5

RTECS: AS3600000

OSHA PEL N/K

ACGIH TLV: N/K

BIS-ACRYLAMIDE DIMETHYL ETHER (MAY CONTAIN ONE OR MORE OF

CAS: 16958-71-7

OSHA PEL N/K

ACGIH TLV: N/K

DIACETONE ACRYLAMIDE (MAY CONTAIN ONE OR MORE OF THE

CAS: 2873-97-4

RTECS: AS3475000

OSHA PEL N/K

ACGIH TLV: N/K

DI(ETHYLENE GLYCOL) DI-ACRYLATE (DEGDA) (MAY CONTAIN ONE OR

CAS: 4074-88-8

RTECS: AS9450000

OSHA PEL N/K

ACGIH TLV: N/K

TETRA (ETHYLENE GLYCOL) DIACRYLATE (TREGDA) (MAY CONTAIN

CAS: 17831-71-9

RTECS: AS8100000

OSHA PEL N/K

ACGIH TLV: N/K

N, N'-METHYLENE-BIS-ACRYLAMIDE (MAY CONTAIN ONE OR MORE OF

CAS: 110-26-9

RTECS: AS3678000

OSHA PEL N/K

ACGIH TLV: N/K

T;

CAS: 79-06-1

RTECS: AS3325000

OSHA PEL 0.3 MG/M3

ACGIH TLV: 0.03 MG/M3

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

LD50 LC50 Mixture:SEE TOXICOLOGICAL INFORMATION.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:POTENTIAL HLTH EFTS: CARCIN -
ACRYLAMIDE IS A PROBABLE HUMAN CARCIN & A HUMAN NEUROTOXIN. ANOTHER
MINOR COMPONENT HAS BEEN SHOWN TO CAUSE CANCER IN LAB ANIMALS & IS
ALSO NEUROTOXIC. MAY BE IRRITATING TO EYES, SKIN & RESP TRACT.
EXPOS TO FORMALDEHYDE MAY PRDCE ALLERGIC RESP EFTS IN SENSITIZED
INDIVIDUALS, INCL ASTHMA, COUGHING, WHEEZING, SHORTNESS OF BREATH.
FORMALDEHYDE IS ALSO CONSIDERED A PROBAB LE HUMAN CARCIN. APS IS
MODERATELY TOX BY INGEST & MAY BE IRRITATING TO EYES, SKIN, THROAT
& NOSE. MAY PRODUCE ALLERGIC RESP & SKIN EFTS IN SENSITIZED
INDIVIDUALS.
Explanation of Carcinogenicity:ACRYLAMIDE: IARC MONO, SUPP, VOL 7, PG
56, 1998: GRP 2B. NTP 8TH ANNUAL RPT ON CARCINS, 1998: REASONABLY
ANTIC TO BE ANIMAL CARCIN. ANIMAL: CNS TOXIN, NEOPLASMS.
FORMALDEHYDE: IARC MONO, SUPP, VOL 62, PG 217, 1995: GRP 2A. NTP
8TH ANNUAL RPT ON CARCINS, 1998: REASONABLY ANTIC TO BE ANIMAL
CARCIN. OSHA REGULATED: CFR 29 1910.1048. ANIMAL: NASAL TUMORS.
Effects of Overexposure:SEE HLTH HAZS. --SARA REGS: & ARE IRRITATING TO
SKIN, EYES & RESP TRACT. FORMALDEHYDE CAUSES IRRIT TO EYES, NOSE,
THROAT & RESP TRACT AT LOW CONCS (<1 PPM). DFCLTY IN BRTHG MAY
OCCUR AT 10-20 PPM, W/S ERIOUS INJURY TO RESP TRACT AT 50 PPM.
EXPOS TO FORMALDEHYDE MAY PRDCE ALLERGIC RESP EFTS, INCL ASTHMA, IN
SENSITIZED INDIVIDUALS. DIETHYLENE GLYCOL DIACRYLATE IS CORR TO
EYES (CAUSES SEV CORNEAL DMG) & SKIN, & HAS BEEN REPORTED TO BE A
SKIN SENSITIZER. TETRAETHYLENE GLYCOL DIACRYLATE IS MOD IRRITATING
TO SKIN W/ACUTE EXPOS & CORR TO EYES. IT HAS ALSO BEEN REPORTED AS
SKIN SENSITIZER. CONT NEHC FO R MORE INFO ON TOXIC EFTS .

First Aid:EYES: FLUSH W/WATER FOR AT LEAST 15 MINS. IF IRRIT OCCURS &
PERSISTS, CONT MD. SKIN: REMOVE CONTAM CLTHG & SHOES, & THORO WASH
W/SOAP & WATER. IF IRRIT OCCURS & PERSISTS, CONT MD. INHAL: REMOVE
TO FRE SH AIR. IF BRTHG DFCLTY/DISCOMFORT OCCURS & PERSISTS, CONT
MD. INGEST: DRINK 1-2 GLASSES OF WATER & INDUCE VOMIT BY TOUCHING
BACK OF THROAT W/FINGER OR BY GIVING SYRUP OF IPECAC. NEVER INDUCE
VOMIT/GI VE ANYTHING BY MOUTH TO AN UNCON PERS. CONT MD. NOTES TO
MD: SINGEL MAY PRDCE EYE, SKIN & RESP TRACT IRRIT & HAS MOD ORAL
TOX. ACRYLAMIDE IS A HUMAN NEUROTOXIN W/BOTH CENTRAL & PERIPHERAL
NERV SYS EFT S & NO SPECIFIC ANTIDOTE. (SUP DAT)

Extinguishing Media:USE CARBON DIOXIDE, DRY CHEMICAL POWDER, ALCOHOL OR
POLYMER FOAM, OR WATER SPRAY.
Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:ONE OF THE COMPONENTS CONTAINS A STRONG
OXIDIZER. CONTACT WITH COMBUSTIBLE MATERIALS, FLAMMABLE MATERIALS,
OR POWDERED METALS CAN CAUSE FIRE OR EXPLOSION. BURNING MAY PRODUCE
CARBON MONOXIDE AND/OR CA RBON DIOXIDE, AMMONIA, NITROUS OXIDES,
SULFUR OXIDES, AND SULFURIC ACID.

Spill Release Procedures:ABSORB ON ABSORBENT MATERIAL AND PLACE INTO
CLOSED CONTAINERS FOR LATER DISPOSAL. FLUSH AREA WITH WATER.
MATERIAL SUBLIMES; THEREFORE, CLEAN UP SPILLS BEFORE THEY DRY. FOR
PERSONAL PRECAUTIONS SEE CON TROL MEASURES SECTION.

Handling and Storage Precautions:STORE IN A COOL (UNDER OR EQUAL TO
25C) DRY AREA AWAY FROM COMBUSTIBLES.

Respiratory Protection:USE EXHAUST VENTILATION OR WEAR RESPIRATORS
WHICH ARE APPROVED BY NIOSH, EC CEN, OR OTHER COMPARABLE
CERTIFICATION ORGANIZATIONS.
Ventilation:USE EXHAUST VENTILATION.
Protective Gloves:CHEMICAL-RESISTANT GLOVES SHOULD BE WORN.
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:NOT REQUIRED. LAB COAT OR EQUIVALENT
RECOMMENDED. ANSI APPROVED EMERGENCY EYEWASH AND DELUGE SHOWER .
Work Hygienic Practices:AVOID ALL CONTACT. CAREFUL PERSONAL HYGIENE IS
A NECESSITY.
Supplemental Safety and Health
FIRST AID PROC: TREATMENT IS CONTROLLED REMOVAL OF EXPOS W/SYMPTOMATIC
& SUPPORTIVE CARE. PHYSICAL/CHEM PROPERTIES: FOR LIQ COMPONENTS:
BP: ABOUT 100C/212F; MP: N/A; VP/VAP DENS/SPEC GRAV: N/K; PH: N/ A;
EVAP RATE: AS WATER; SOL IN WATER: AQUEOUS SOLN; % VOLATS: 50-95%
WATER; MOLECULAR WT: N/A; (OTHER INFO)

Boiling Pt:B.P. Text:SUP DAT
Melt/Freeze Pt:M.P/F.P Text:SUP DAT
Vapor Pres:SUP DAT
Vapor Density:SUP DAT
Spec Gravity:SUP DAT
pH:SUP DAT
Evaporation Rate & Reference:SUP DAT
Solubility in Water:SUP DAT
Appearance and Odor:SUP DAT
Percent Volatiles by Volume:SUP DAT

Stability Indicator/Materials to Avoid:YES
AVOID STRONG REDUCING AGENTS, ORGANIC MATERIALS, FINELY POWDERED
METALS.
Stability Condition to Avoid:POWDERED COMPONENTS MAY DECOMPOSE ON
EXPOSURE TO MOIST AIR OR WATER.
Hazardous Decomposition Products:UNDER FIRE IT CAN RELEASE TOXIC FUMES
OF CARBON MONOXIDE, CARBON DIOXIDE, AMMONIA, AND NITROGEN OXIDES.
Conditions to Avoid Polymerization:LIQ COMPONENT CAN UNDERGO POLYM IF
EXPOSED TO HEAT/ULTRAVIOLET LIGHT. IF POLYM OCCURS IN CLSD CONTR,
SUFFICIENT (OTHER INFO)

Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH APPLICABLE LOCAL,
STATE/PROVINCIAL, AND FEDERAL/NATIONAL REGULATIONS.

Toxicological Information:SKIN CONT: UREA: MILD IRRITANT (HUMAN), RTECS
1995. BUFFER SOLN: NO DATA AVAIL FOR FORMULATION. AMMONIUM
PERSULFATE: NON-IRRITATING (RABBIT). MAY BE SENSITIZER TO ALLERGIC
INDIVIDUALS. I87-0970. GEL S OLN: NO DATA AVAIL FOR FORMULATION.
ACRYLAMIDE: MILD TO MOD IRRITANT (RABBIT) DOC TLVS 1986, GOSSELIN
1984. FORMALDEHYDE: MOD IRRITANT (RABBIT) MILD IRRITANT (HUMAN).
SKIN SENSITIZER, RTECS 1985, IARC 1982. NMA: MILD TO MOD IRRITANT
(RABBIT) NTP TRS 352. DEGDA: CORR; SEV IRRITATING SKIN SENSITIZER.
PATTY'S 1994, J. TOXICOL ENVIRON HLTH 19:149 1986. TREDGA: MOD
IRRITANT (RABBIT); RPTD EXPOS ( 2 WKS ) CORR; (ECOLOGICAL INFO)

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:ENVIRON FATE: NO DATA AVAIL. ENVIRON EFT: AMMONIUM
PERSULFATE: BLUEGILL SUNFISH 96 HR LC50=103 MG/L (L92-1246);
RAINBOW TROUT 96 HR LC50=76.3 MG/L (L92-1247); DAPHNIA 48 HR
LC50=120 MG/L (192-1248); G RASS SHRIMP 96 HR LC50=391 MG/L
(L92-1249). --TOX INFO: SKIN SENSITIZER. J. TOXICOL ENVIRON HLTH
19:149 1986. SKIN ABSORPTION: BUFFER SOLN: NO DATA AVAIL FOR
FORMULATION. AMMONIUM PERSULFATE: LD50 >20 00 MG/KG (RAT) I91-1200.
UREA: NO DATA AVAIL. GEL SOLN: DERMAL LD50 >1000 MG/KG (RABBIT); NO
MORTALITY I97-2199. INHAL: GEL SOLN: NO DATA AVAIL FOR FORMULATION.
NMA: LC50 = 5 MG/L (4 HR RAT) CYTEC MSD S 1994. (TRANSPORT INFO)

Transport Information:U.S. DOT/ICAO/IATA/CANADA (TDG): FOR AMMONIUM
PERSULFATE. UN #: UN1444. PACKAGING GRP: CLASS III. HAZ LABEL:
OXIDIZER. HAZ CLASS: 5.1. --ECOLOGICAL INFO: FORMALDEHYDE: LC50 =
0.59 MG/L (RAT), RESP SEN SITIZER, RTECS 1995, DOC TLVS 1991.
AMMONIUM PERSULFATE: LC50 >2.95 MG/L (4 HR RAT), MAX ATTAINABLE
CONC (DUST) I87-0969. UREA: NO DATA AVAIL. BUFFER SOLN: NO DATA
AVAIL FOR FORMULATION. INGEST: UREA: LD50 = 8471 MG/KG (RAT),
RTECS 1995. BUFFER SOLN: NO DATA AVAIL FOR FORMULATION. AMMONIUM
PERSULFATE: LD50 = 495 MG/KG (RAT), I91-1201. GEL SOLN: ORAL LD50
>500 MG/KG (RAT) STILLMEADOW 3 1997, I97-21 98. EYE CONT: UREA: NO
DATA(SARA REGS)

SARA Title III Information:NOT LISTED. SECTIONS 311/312, & 313 (40 CFR
372): NOT LISTED. --TRANSPORT INFO: AVAIL. BUFFER SOLN/GEL SOLN: NO
DATA AVAIL FOR FORMULATION. AMMONIUM PERSULFATE: MIN IRRITATING
(RABBIT), I87-0968. ACRY LAMIDE: MOD TO SEV IRRITANT (RABBIT), DOC
TLVS 1986, GOSSELIN 1984. RTECS 1983. FORMALDEHYDE: SEV IRRITANT
RTECS 1985. NMA: MILD TO MOD IRRITANT NTP TRS 352. DEGDA: CORR; SEV
IRRITATING. PATTY'S 1994, J. TOXICOL ENVIRON HLTH 19:149 1986.
TREDGA: CORR. J. TOXICOL ENVIRON HLTH 19:149 1985. ACUTE EFTS FROM
OVEREXP: FORMULATION IN COMPARTMENT 4 MAY BE HARMFUL BY INGEST.
ACRYLAMIDES ARE READILY ABSORBE D THRU SKIN & BY INHAL,(EFTS OF
OVEREXP)
Federal Regulatory Information:U.S. TSCA INVENTORY: ACRYLAMIDE,
AMMONIUM PERSULFATE, & FORMALDEHYDE ARE LISTED. CANADA WHMIS: D. 2A
(VERY TOX MATL, CARCIN; RESP SENSITIZER, MUTAGEN); C (OXIDIZING
MATL); D. 2B (MATLS CAUSING OTHER T OX EFTS). EINECS #: NONE FOR
LIQ FORMULATIONS. (AMMONIUM PERSULFATE 231-786-5, ACRYLAMIDE
201-173-7, FORMALDEHYDE 200-001-8). EC SYMBOLS: T (TOX); O
(OXIDIZER); XN (HARMFUL). EC RISK PHRASES: R 8 CONT W/COMBUST MATL
MAY CAUSE FIRE; R 22 HARMFUL IF SWALLOWED; R 45 MAY CAUSE CANCER; R
46 MAY CAUSE HER ITABLE GENETIC DMG; R 42/43 MAY CAUSE SENSIT BY
INHAL & SKIN CONT; R 24/25 TOX IN CONT W/SKIN & IF SWALLOWED;
(STATE REGS)
State Regulatory Information:CALIFORNIA PROPOSITION 65: WARNING: THIS
PROD CONTAINS CHEMS KNOWN TO STATE OF CALIFORNIA TO CAUSE CANCER.
--FED REGS: R 48/23/24/25 TOX: DANGER OF SERIOUS DMG TO HLTH BY
PRLNG EXPOS THRU INHAL, IN CO NT W/SKIN & IF SWALLOWED. EC SFTY
ADVISE PHRASES: S 53 AVOID EXPOS - OBTAIN SPECIAL INSTRUCTIONS
BEFORE USE; S 45 IN CASE OF ACCIDENT/IF YOU FEEL UNWELL, SEEK MED
ADVICE IMMED (SHOW LABEL WHERE POSS). THIS PROD CONTAINS
SUBSTANCES NOT YET FULLY TESTED. THIS DOCUMENT HAS BEEN PREPARED TO
MEET REQS OF U.S. OSHA HAZ COMMUNICATION STD, 29 CFR 1910.1200; EC
DIRECTIVE, 91/155/EEC, & OTHER REGULATORY REQS.